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Supplementary information

This supplementary information provides the NMR spectra of antarlide F, antarlide G, and antarlide H in Acetone-d6 solvent, along with their respective COSY, HMQC, HMBC, and NOESY spectra. Additionally, it includes a PDA chromatogram showing the photoisomerization of antarlide A and antarlide F after exposure to room light for 2 hours.

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Supplementary information

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  1. Supplementary information

  2. Figure S1. 1H NMR spectrum of antarlide F (500 MHz, Acetone-d6) Figure S2. 13C NMR spectrum of antarlide F (125 MHz, Acetone-d6)

  3. Figure S3. 1H-1H COSY spectrum of antarlide F (500 MHz, Acetone-d6) Figure S4. HMQC spectrum of antarlide F (500 MHz, Acetone-d6)

  4. Figure S5. HMBC spectrum of antarlide F (500 MHz, Acetone-d6) Figure S6. NOESY spectrum of antarlide F (500 MHz, Acetone-d6)

  5. Figure S7. COSY (bold), key HMBC (arrow) and key NOESY (dashed arrow) correlations for antarlide F

  6. Figure S8. 1H NMR spectrum of antarlide G (500 MHz, Acetone-d6) Figure S9. 13C NMR spectrum of antarlide G (125 MHz, Acetone-d6)

  7. Figure S10. 1H-1H COSY spectrum of antarlide G (500 MHz, Acetone-d6) Figure S11. HSQC spectrum of antarlide G (500 MHz, Acetone-d6)

  8. Figure S12. HMBC spectrum of antarlide G (500 MHz, Acetone-d6) Figure S13. Selective HMBC spectrum of antarlide G (600 MHz, Acetone-d6)

  9. Figure S14. NOESY spectrum of antarlide G (500 MHz, Acetone-d6)

  10. Figure S15. 1H NMR spectrum of antarlide H (500 MHz, Acetone-d6) Figure S16. 13C NMR spectrum of antarlide H (125 MHz, Acetone-d6)

  11. Figure S17. 1H-1H COSY spectrum of antarlide H (500 MHz, Acetone-d6) Figure S18. HMQC spectrum of antarlide H (500 MHz, Acetone-d6)

  12. Figure S19. HMBC spectrum of antarlide H (500 MHz, Acetone-d6) Figure S20. Selective HMBC spectrum of antarlide H (600 MHz, Acetone-d6)

  13. Figure S21. NOESY spectrum of antarlide H (500 MHz, Acetone-d6)

  14. Figure S22. COSY (bold), key HMBC (arrow) and key NOESY (dashed arrow) correlations for antarlide H

  15. Figure S23. Photoisomerization of antarlide A and antarlide F PDA chromatogram of antarlide A, antarlide A which is exposed to the room light for 2 hour, antarlide F, and antarlide Fwhich is exposed to the room light for 2 hour (solvent : MeCN:H2O=1:1).

  16. Antarlide A A Antarlide A light 2 h A E F Antarlide F F Antarlide F light 2 h F A E

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